Phosphinites derived from the 7-phosphanorbornene skeleton: First results in asymmetric catalysis

被引：22

作者：

Clochard, M ^{[1
]}

Mattmann, E ^{[1
]}

Mercier, F ^{[1
]}

Ricard, L ^{[1
]}

Mathey, F ^{[1
]}

机构：

[1] Ecole Polytech, DCPH, CNRS, UMR 7653,Lab Heteroelements & Coordinat, F-91128 Palaiseau, France

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 17期

关键词：

D O I：

10.1021/ol035067g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The bisphosphinite 4 incorporating two 7-phosphanorbornene subunits is an efficient ligand for the Rh-catalyzed enantioselective hydrogenation of functional alkenes in terms of rate and enantioselectivity. This type of structures is readily accessible by [4 + 2] cycloaddition of phospholes with dienophilic alkenes and can be easily fine-tuned.

引用

页码：3093 / 3094

页数：2

共 13 条

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