Cathodoluminescence of Cu(In,Ga)Se2 thin films used in high-efficiency solar cells

被引:75
作者
Romero, MJ [1 ]
Ramanathan, K [1 ]
Contreras, MA [1 ]
Al-Jassim, MM [1 ]
Noufi, R [1 ]
Sheldon, P [1 ]
机构
[1] Natl Renewable Energy Lab, Golden, CO 80401 USA
关键词
D O I
10.1063/1.1631083
中图分类号
O59 [应用物理学];
学科分类号
摘要
Cathodoluminescence spectroscopy and spectrum imaging are employed to investigate Cu(In,Ga)Se-2 (CIGS) thin films used in high-efficiency solar cells. We have found a nonuniform spatial distribution for the photon energy. The shift by decade of the emission spectrum is also found to depend systematically on the location of excitation. In addition, the photon energy at grain boundaries is not affected by the external excitation. A model for radiative recombination to be applied to these chalcopyrite compounds should explain these results, and some suggestions are considered. (C) 2003 American Institute of Physics.
引用
收藏
页码:4770 / 4772
页数:3
相关论文
共 13 条
  • [1] Radiative recombination via intrinsic defects in CuxGaySe2
    Bauknecht, A
    Siebentritt, S
    Albert, J
    Lux-Steiner, MC
    [J]. JOURNAL OF APPLIED PHYSICS, 2001, 89 (08) : 4391 - 4400
  • [2] Contreras MA, 1999, PROG PHOTOVOLTAICS, V7, P311, DOI 10.1002/(SICI)1099-159X(199907/08)7:4<311::AID-PIP274>3.0.CO
  • [3] 2-G
  • [4] RADIATIVE LIFETIMES OF DONOR-ACCEPTOR PAIRS IN P-TYPE GALLIUM ARSENIDE
    DINGLE, R
    [J]. PHYSICAL REVIEW, 1969, 184 (03): : 788 - &
  • [5] Postgrowth thermal treatment of CuIn(Ga)Se2:: Characterization of doping levels in In-rich thin films
    Dirnstorfer, I
    Hofmann, DM
    Meister, D
    Meyer, BK
    [J]. JOURNAL OF APPLIED PHYSICS, 1999, 85 (03) : 1423 - 1428
  • [6] Dirnstorfer I, 1998, PHYS STATUS SOLIDI A, V168, P163, DOI 10.1002/(SICI)1521-396X(199807)168:1<163::AID-PSSA163>3.0.CO
  • [7] 2-T
  • [8] Properties of 19.2% efficiency ZnO/CdS/CuInGaSe2 thin-film solar cells
    Ramanathan, K
    Contreras, MA
    Perkins, CL
    Asher, S
    Hasoon, FS
    Keane, J
    Young, D
    Romero, M
    Metzger, W
    Noufi, R
    Ward, J
    Duda, A
    [J]. PROGRESS IN PHOTOVOLTAICS, 2003, 11 (04): : 225 - 230
  • [9] Shklovskii B. I., 1984, ELECT PROPERTIES DOP
  • [10] Effects of Ga addition to CuInSe2 on its electronic, structural, and defect properties
    Wei, SH
    Zhang, SB
    Zunger, A
    [J]. APPLIED PHYSICS LETTERS, 1998, 72 (24) : 3199 - 3201