Nickel-catalyzed decarbonylative addition of phthalimides to alkynes

被引：173

作者：

Kajita, Yuichi ^{[1
]}

Matsubara, Seijiro ^{[1
]}

Kurahashi, Takuya ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6158510, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 19期

关键词：

D O I：

10.1021/ja7114426

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An intermolecular nickel-catalyzed addition reaction has been developed where N-arylphthalimides react with alkynes to afford substituted isoquinolones. A mechanistic rationale is proposed, implying nucleophilic attack of Ni(0) to an amide as the primary step of the catalytic cycle.

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页码：6058 / +

页数：3

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