Identifiability of competitive intermolecular three-state excited-state processes

被引：7

作者：

Boens, N

Kowalczyk, A

机构：

[1] Department of Chemistry, Katholieke Universiteit Leuven

[2] Institute of Physics, Nicholas Copernicus University

来源：

CHEMICAL PHYSICS LETTERS | 1996年 / 260卷 / 3-4期

关键词：

D O I：

10.1016/0009-2614(96)00859-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The conditions necessary for the recovery of the rate constants from fluorescence decay traces due to competitive intermolecular three-state excited-state processes are investigated. The studied system models a situation where an excited-state species can react competitively with both co-reactants X and Y. It is demonstrated theoretically that, if fluorescence decay traces at two concentrations of X and two concentrations of Y are available, all seven rate constants can always be recovered. In contrast to previously studied intermolecular two-state and three-state excited-state processes, it is not required to obtain a fluorescence decay at [X] = [Y] = 0 M to assign unique numerical values to all rate constants.

引用

页码：326 / 330

页数：5

共 11 条

[1] NON A PRIORI ANALYSIS OF FLUORESCENCE DECAY SURFACES OF EXCITED-STATE PROCESSES .1. THEORY [J].