Highly Ordered Mesoporous MoS2 with Expanded Spacing of the (002) Crystal Plane for Ultrafast Lithium Ion Storage

被引:477
作者
Liu, Hao [1 ]
Su, Dawei [2 ]
Zhou, Ruifeng [1 ]
Sun, Bing [2 ]
Wang, Guoxiu [2 ]
Qiao, Shi Zhang [1 ,3 ]
机构
[1] Univ Queensland, Australian Inst Bioengn & Nanotechnol, ARC Ctr Excellence Funct Nanomat, Brisbane, Qld 4072, Australia
[2] Univ Technol Sydney, Sch Chem & Forens Sci, Ctr Clean Energy Technol, Broadway Sydney, NSW 2007, Australia
[3] Univ Adelaide, Sch Chem Engn, Adelaide, SA 5005, Australia
基金
澳大利亚研究理事会;
关键词
anodes; lithium ion batteries; mesoporous; molybdenum sulphides; lithium ion storage; ANODE MATERIAL; HIGH-CAPACITY; INTERCALATION; PERFORMANCE; ELECTRODES;
D O I
10.1002/aenm.201200087
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Highly ordered mesoporous MoS 2 with a high surface area and narrow pore-size distribution is synthesized by a vacuum assisted impregnation route. The mesoporous MoS 2 demonstrates an expanded d 002 spacing of 0.66 nm. The mesoporous MoS 2 electrode achieves an excellent high rate capacity of 608 mAh g -1 at the discharge current of 10 A g -1 (-15C), which places MoS 2 as a viable next generation high power source for electric vehicles. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:970 / 975
页数:6
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