The FT-IR spectra of pyrazinamide complexes of transition metal(II) tetracyanonickelate

被引：27

作者：

Akyuz, S ^{[1
]}

机构：

[1] Istanbul Univ, Dept Phys, TR-34459 Istanbul, Turkey

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2003年 / 651卷

关键词：

infrared spectra; Hofmann type complexes; tetracyanonickelate; transition metal; pyrazinamide; pyrazine carboxamide;

D O I：

10.1016/S0022-2860(02)00675-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

M(PZA)(2)Ni(CN)(4) (where M = Mn, Co,Fe, Ni or Cd; PZA = pyrazinamide} complexes have been prepared for the first time and their FT-IR spectra are reported in the 400-4000 cm(-1) region. The spectral features suggest that the compounds are similar in structure to the Hofmann type two dimensional coordination polymer compounds, formed with Ni(CN)(4)(-2) ions bridged by M(PZA)(2)(+2) cations. PZA is coordinated to M(II) through the oxygen atom of the carbonyl group. (C) 2002 Elsevier Science B.V. All rights reserved.

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页码：541 / 545

页数：5

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