Study of the thermal stability of phases in the Mg-Al system

被引:23
作者
Czeppe, T [1 ]
Zakulski, W [1 ]
Bielanska, E [1 ]
机构
[1] Polish Acad Sci, Aleksander Krupkowski Inst Met & Mat Sci, PL-30059 Krakow, Poland
来源
JOURNAL OF PHASE EQUILIBRIA | 2003年 / 24卷 / 03期
关键词
D O I
10.1361/105497103770330550
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A part of the Al-Mg phase diagram was studied in the range of composition between 48 and 61 at.% Al by DSC and SEM/EDS methods. The temperature ranges of stability of the beta, gamma, and epsilon, phases were considered. It was found that the congruent melting temperature of the beta phase was 450 +/- 1 degreesC. The Al content in that phase was determined to be 61 +/- 1 at.% Al at 420 degreesC. The upper temperature limit of the stability of the F phase was established to be 427 +/- 1 degreesC. The Al content changed from 54 at.% at 390 degreesC to 56 at.%, at 420 degreesC. The lower temperature limit of the epsilon phase formation was not determined, as a result of a slow epsilon = beta + gamma reaction. The hypothetical lambda or zeta phases were not found, but it was observed that decomposition of oxides might produce extra thermal effects.
引用
收藏
页码:249 / 254
页数:6
相关论文
共 10 条
[1]  
Donnadieu P, 1997, Z METALLKD, V88, P33
[2]  
Donnadieu P, 1996, J PHYS I, V6, P1153, DOI 10.1051/jp1:1996121
[3]  
Donnadieu P, 1998, PHILOS MAG A, V78, P893, DOI 10.1080/01418619808239963
[4]   AN EXPERIMENTAL-TECHNIQUE FOR THE RAPID-DETERMINATION OF BINARY PHASE-DIAGRAMS - THE AL-MG SYSTEM [J].
GOEL, NC ;
CAHOON, JR ;
MIKKELSEN, B .
METALLURGICAL TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1989, 20 (02) :197-203
[5]  
HANSEN M, 1958, CONSTITUTION BINARY, P105
[6]  
HULTGREN R, 1973, SELECTED VALUES THER, P182
[7]  
Liang P, 1998, Z METALLKD, V89, P536
[8]  
Murray JL., 1982, B ALLOY PHASE DIAGRA, V3, P60, DOI [10.1007/BF02873413, DOI 10.1007/BF02873413]
[9]  
SCHURMANN E, 1981, GIESSEREIFORSCHUNG, V33, P43
[10]   Experimental investigation of the Mg-Al phase diagram from 47 to 63 at% Al [J].
Su, HL ;
Harmelin, M ;
Donnadieu, P ;
Baetzner, C ;
Seifert, HJ ;
Lukas, HL ;
Effenberg, G ;
Aldinger, F .
JOURNAL OF ALLOYS AND COMPOUNDS, 1997, 247 :57-65