Facile synthesis and photoluminescence of europium ion doped LaF3 nanodisks

被引:53
作者
Zhu, Ling
Meng, Iian
Cao, Xueqiang [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Key Lab Rare Earth Chem & Phys, Changchun 130022, Jilin, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
关键词
materials science; crystal growth; rare earths; fluorescence;
D O I
10.1002/ejic.200700390
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
LaF3 : Eu3+ (5.0 mol-% EU3+) nanodisks with perfect crystallinity were successfully synthesized by a simple method. The synthesis was carried out in an aqueous solution at room temperature without the use of templates or organic additives, The mechanism of formation of the nanodisks was explored, and the fluoride source (KBF4) is believed to play a key role in controlling the morphology of the final product. Furthermore, the size of the disk can be simply moderated by varying the concentration of the initial reactants. The room-temperature photoluminescence of LaF3 : Eu3+ with different morphologies and sizes were also investigated, and the results indicate that the emission intensity of the product is strongly affected by their size, shape, and other factors. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).
引用
收藏
页码:3863 / 3867
页数:5
相关论文
共 49 条
[1]  
BROWN TL, 2000, CHEM CENTRAL SCI, P1023
[2]   Chemistry and properties of nanocrystals of different shapes [J].
Burda, C ;
Chen, XB ;
Narayanan, R ;
El-Sayed, MA .
CHEMICAL REVIEWS, 2005, 105 (04) :1025-1102
[3]   Growth of ZnO nanoneedle arrays with strong ultraviolet emissions by an electrochemical deposition method [J].
Cao, BQ ;
Li, Y ;
Duan, GT ;
Cai, WP .
CRYSTAL GROWTH & DESIGN, 2006, 6 (05) :1091-1095
[4]   Single-crystal dendritic micro-pines of magnetic α-Fe2O3:: Large-scale synthesis, formation mechanism, and properties [J].
Cao, MH ;
Liu, TF ;
Gao, S ;
Sun, GB ;
Wu, XL ;
Hu, CW ;
Wang, ZL .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (27) :4197-4201
[5]   A SYSTEMATIC ANALYSIS OF THE SPECTRA OF THE LANTHANIDES DOPED INTO SINGLE-CRYSTAL LAF3 [J].
CARNALL, WT ;
GOODMAN, GL ;
RAJNAK, K ;
RANA, RS .
JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (07) :3443-3457
[6]   The concept of delayed nucleation in nanocrystal growth demonstrated for the case of iron oxide nanodisks [J].
Casula, MF ;
Jun, YW ;
Zaziski, DJ ;
Chan, EM ;
Corrias, A ;
Alivisatos, AP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (05) :1675-1682
[7]   Seedless, surfactantless wet chemical synthesis of silver nanowires [J].
Caswell, KK ;
Bender, CM ;
Murphy, CJ .
NANO LETTERS, 2003, 3 (05) :667-669
[8]   Hydrothermal synthesis and characterization of YVO4-based phosphors doped with Eu3+ ion [J].
Chen, LM ;
Liu, YN ;
Huang, KL .
MATERIALS RESEARCH BULLETIN, 2006, 41 (01) :158-166
[9]   Structure-controlled solventless thermolytic synthesis of uniform silver nanodisks [J].
Chen, YB ;
Chen, L ;
Wu, LM .
INORGANIC CHEMISTRY, 2005, 44 (26) :9817-9822
[10]   Two-step self-assembly of nanodisks into plate-built cylinders through oriented aggregation [J].
Cheng, Y ;
Wang, YS ;
Zheng, YH ;
Qin, Y .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (23) :11548-11551