Synthesis of titanium-containing mesoporous molecular sieves with a cubic structure

被引：151

作者：

Koyano, KA ^{[1
]}

Tatsumi, T ^{[1
]}

机构：

[1] UNIV TOKYO,FAC ENGN,ENGN RES INST,TOKYO 113,JAPAN

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 02期

关键词：

D O I：

10.1039/cc9960000145

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A titanium-containing mesoporous material with a cubic structure, Ti-MCM-48, is synthesized by a two-stage hydrolysis method using tetraethylorthosilicate and tetrabutylorthotitanate and found to be more active than Ti-MCM-41 in the epoxidation of bulky alkenes using H2O2.

引用

页码：145 / 146

页数：2

共 14 条

[1] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES
BECK, JS
VARTULI, JC
ROTH, WJ
LEONOWICZ, ME
KRESGE, CT
SCHMITT, KD
CHU, CTW
OLSON, DH
SHEPPARD, EW
MCCULLEN, SB
HIGGINS, JB
SCHLENKER, JL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) : 10834 - 10843
[2] SYNTHESIS, CHARACTERIZATION, AND CATALYTIC ACTIVITY OF TI-MCM-41 STRUCTURES
BLASCO, T
CORMA, A
NAVARRO, MT
PARIENTE, JP
[J]. JOURNAL OF CATALYSIS, 1995, 156 (01) : 65 - 74
[3] STUDIES ON MESOPOROUS MATERIALS .2. SYNTHESIS MECHANISM OF MCM-41
CHEN, CY
BURKETT, SL
LI, HX
DAVIS, ME
[J]. MICROPOROUS MATERIALS, 1993, 2 (01): : 27 - 34
[4] SYNTHESIS OF AN ULTRALARGE PORE TITANIUM SILICATE ISOMORPHOUS TO MCM-41 AND ITS APPLICATION AS A CATALYST FOR SELECTIVE OXIDATION OF HYDROCARBONS
CORMA, A
NAVARRO, MT
PARIENTE, JP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (02) : 147 - 148
[5] KIM YI, 1991, MATER RES SOC SYMP P, V233, P145
[6] ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM
KRESGE, CT
LEONOWICZ, ME
ROTH, WJ
VARTULI, JC
BECK, JS
[J]. NATURE, 1992, 359 (6397) : 710 - 712
[7] HYDROXY-ASSISTED CHEMOSELECTIVE AND STEREOSELECTIVE EPOXIDATION CATALYZED BY A TITANIUM SILICATE MOLECULAR-SIEVE (TS-1)/H2O2 SYSTEM
KUMAR, R
PAIS, GCG
PANDEY, B
KUMAR, P
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (13) : 1315 - 1316
[8] SYNTHESIS OF MESOPOROUS VANADIUM SILICATE MOLECULAR-SIEVES
REDDY, KM
MOUDRAKOVSKI, I
SAYARI, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (09) : 1059 - 1060
[9] SYNTHETIC AND MECHANISTIC ASPECTS OF METAL-CATALYZED EPOXIDATIONS WITH HYDROPEROXIDES
SHELDON, RA
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1980, 7 (01): : 107 - 126
[10] TITANIUM-CONTAINING MESOPOROUS MOLECULAR-SIEVES FOR CATALYTIC-OXIDATION OF AROMATIC-COMPOUNDS
TANEV, PT
CHIBWE, M
PINNAVAIA, TJ
[J]. NATURE, 1994, 368 (6469) : 321 - 323

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