Syntheses of mixed-ligand ruthenium(II) complexes with a terpyridine or a tris(pyrazolyl)methane and a bidentate ligand: their application for catalytic hydroxylation of alkanes

被引：23

作者：

Yamaguchi, M ^{[1
]}

Iida, T ^{[1
]}

Yamagishi, T ^{[1
]}

机构：

[1] Tokyo Metropolitan Univ, Grad Sch Engn, Dept Appl Chem, Tokyo 1920397, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1998年 / 1卷 / 08期

关键词：

oxidation catalyst; alkane hydroxylation; ruthenium complexes; mixed-ligand complexes;

D O I：

10.1016/S1387-7003(98)00080-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new mixed-ligand chlororuthenium(II) complexes [RuCl(L) (tpy)]Cl-n and [RuCl(L) (tpm)] Cl-n(L = bpy, dmpa or dmgly; n = 0 or 1) were prepared, and the catalytic activity for alkane oxidation using m-chloroperbenzoic acid was examined. Alcohol was the main product: oxidation of adamantane, cyclooctane or ethylbenzene gave hydroxylated products, 1-adamantanol (66%), cyclooctanol (22%) or 1-phenylethanol (48%), respectively. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：299 / 301

页数：3

共 23 条

[1] METAL-LIGAND MULTIPLE BONDS - OXO, IMIDO AND NITRIDO COMPLEXES OF RUTHENIUM AND OSMIUM [J].

CHE, CM .

PURE AND APPLIED CHEMISTRY, 1995, 67 (02) :225-232

[2] HIGH-VALENT COMPLEXES OF RUTHENIUM AND OSMIUM [J].

CHE, CM ;

YAM, VWW .

ADVANCES IN INORGANIC CHEMISTRY, 1992, 39 :233-325

[3] TUNING THE REACTIVITIES OF RUTHENIUM-OXO COMPLEXES WITH ROBUST LIGANDS - A RUTHENIUM(IV)-OXO COMPLEX OF 6,6'-DICHLORO-2,2'-BIPYRIDINE AS AN ACTIVE OXIDANT FOR STOICHIOMETRIC AND CATALYTIC ORGANIC OXIDATION [J].

CHE, CM ;

HO, C ;

LAU, TC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (08) :1901-1907

[4]

Cheng W. - C., 1994, CHEM COMMUN, P1063

[5] REACTIONS OF NONHEME IRON(II) CENTERS WITH DIOXYGEN IN BIOLOGY AND CHEMISTRY [J].

FEIG, AL ;

LIPPARD, SJ .

CHEMICAL REVIEWS, 1994, 94 (03) :759-805

[6] CATALYTIC-OXIDATION OF HYDROCARBONS WITH O2 OR H2O2 USING A STERICALLY HINDERED RUTHENIUM COMPLEX [J].

GOLDSTEIN, AS ;

BEER, RH ;

DRAGO, RS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (06) :2424-2429

[7]

ITO M, 1997, OXYGENASES MODEL SYS, P345

[8]

KAHN MMT, 1992, J MOL CATAL, V77, P221

[9] Fe(TPA)-catalyzed alkane hydroxylation can be a metal-based oxidation [J].

Kim, JH ;

Kim, C ;

Harrison, RG ;

Wilkinson, EC ;

Que, L .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 117 (1-3) :83-89

[10] First example of a rigid (mu-oxo-di-mu-acetato)diiron(III) complex with 1,2-bis[2-di(2-pyridyl)methyl-6-pyridyl]ethane; Its efficient catalysis for functionalization of alkanes [J].

Kodera, M ;

Shimakoshi, H ;

Kano, K .

CHEMICAL COMMUNICATIONS, 1996, (15) :1737-1738

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