Synthesis of tricholomenyn A and epitricholomenyn A by a palladium-catalysed beta-halo enone coupling route

被引：26

作者：

Graham, AE ^{[1
]}

Taylor, RJK ^{[1
]}

机构：

[1] UNIV YORK,DEPT CHEM,YORK YO1 5DD,N YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1997年 / 08期

关键词：

D O I：

10.1039/a700980a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of tricholomenyn A is described via a route employing two palladium-catalysed Sonogashira coupling reactions; an efficient, stereoselective route to epitricholomenyn A is also reported.

引用

页码：1087 / 1089

页数：3

共 21 条

[1] The first total synthesis of a member of the manumycin family of antibiotics: Alisamycin
Alcaraz, L
Macdonald, G
Kapfer, I
Lewis, NJ
Taylor, RJK
[J]. TETRAHEDRON LETTERS, 1996, 37 (36) : 6619 - 6622
[2] Palladium-catalyzed cross-coupling reactions of arylmetal compounds with beta-substituted alpha-iodoenones and a cyclohexyl triflate
Bosse, F
Tunoori, AR
Niestroj, AJ
Gronwald, O
Maier, ME
[J]. TETRAHEDRON, 1996, 52 (28) : 9485 - 9498
[3] CAMPBELL IB, 1994, ORGANOCOPPER REAGENT, pCH10
[4] CORNELIS A, 1995, ENCY REAGENTS ORGANI, P3667
[5] Tricholomenyns C, D, and E, novel dimeric dienyne geranyl cyclohexenones from the fruiting bodies of Tricholoma acerbum
Garlaschelli, L
Vidari, G
VitaFinzi, P
[J]. TETRAHEDRON LETTERS, 1996, 37 (34) : 6223 - 6226
[6] GARLASCHELLI L, 1995, TETRAHEDRON LETT, V36, P5633
[7] SYNTHESIS OF BROMOXONE
GAUTIER, ECL
LEWIS, NJ
MCKILLOP, A
TAYLOR, RJK
[J]. TETRAHEDRON LETTERS, 1994, 35 (47) : 8759 - 8760
[8] GAUTIER ECL, 1997, IN PRESS TETRAHEDRON, V38
[9] Sonogashira coupling reactions of highly oxygenated vinyl halides: The first synthesis of harveynone and epi-harveynone
Graham, AE
McKerrecher, D
Davies, DH
Taylor, RJK
[J]. TETRAHEDRON LETTERS, 1996, 37 (41) : 7445 - 7448
[10] UNPRECEDENTED CONSTITUENTS OF A NEW SPECIES OF ACORN WORM
HIGA, T
OKUDA, RK
SEVERNS, RM
SCHEUER, PJ
HE, CH
XU, CF
CLARDY, J
[J]. TETRAHEDRON, 1987, 43 (06) : 1063 - 1070

← 1 2 3 →