Conversion of mixtures of methane and acetylene or ethylene into higher molecular weight hydrocarbons over metal-loaded and unloaded HZSM-5 zeolite catalysts

被引：16

作者：

Alkhawaldeh, A ^{[1
]}

Wu, XC ^{[1
]}

Anthony, RG ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem Engn, Kinet Catalysis & React Engn Lab, College Stn, TX 77843 USA

来源：

CATALYSIS TODAY | 2003年 / 84卷 / 1-2期

关键词：

methane conversion; acetylene conversion; ethylene conversion; modified HZSM-5;

D O I：

10.1016/S0920-5861(03)00299-2

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A mixture of acetylene and hydrogen was reacted over HZSM-5 zeolite catalyst at 200 degreesC to produce ethylene. A stream containing ethylene and methane was then reacted over gallium-loaded and copper-loaded ZSM-5 to produce higher molecular weight hydrocarbons. The effect of co-feeding methanol or chloroform on the product distribution was also investigated. On the other hand, a mixture of acetylene and methane was reacted over metal-loaded ZSM-5 catalysts to produce higher molecular weight hydrocarbons with a carbon number of five and more. Palladium,, platinum, and nickel were among the transition metals tested. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：43 / 49

页数：7

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