NOx release from a noble metal/BaO catalyst:: dependence on gas composition

被引:87
作者
Amberntsson, A [1 ]
Persson, H
Engström, P
Kasemo, B
机构
[1] Chalmers Univ Technol, Competence Ctr Catalysis, SE-41296 Gothenburg, Sweden
[2] Chalmers Univ Technol, Dept Appl Phys, SE-41296 Gothenburg, Sweden
关键词
NOx; storage; lean-burn; NOx reduction; barium oxide; NOx release;
D O I
10.1016/S0926-3373(00)00266-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Automotive lean-NOx has become one of the major issues in catalysis research, due to increased environmental concerns. In the present study the NOx storage/release concept has been investigated with respect to the NOx release kinetics. The importance of the gas composition during NOx release, including the lambda -value, humidity, O-2, and CO2 concentration, was studied in flow reactor experiments performed with a commercial, noble metal BaO type catalyst. The main conclusions are that CO2 has a promoting and O-2 a blocking effect on the NO, release. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:27 / 38
页数:12
相关论文
共 16 条
[1]  
ACKE F, 1998, THESIS GOTHENBURG U
[2]  
[Anonymous], EARTH SIEGE AIR POLL
[3]   Influence of CO2 on storage and release of NOx on barium-containing catalyst [J].
Balcon, S ;
Potvin, C ;
Salin, L ;
Tempère, JF ;
Djéga-Mariadassou, G .
CATALYSIS LETTERS, 1999, 60 (1-2) :39-43
[4]   Removal of nitrogen oxides from the exhaust of a lean-tune gasoline engine [J].
Bogner, W ;
Kramer, M ;
Krutzsch, B ;
Pischinger, S ;
Voigtlander, D ;
Wenninger, G ;
Wirbeleit, F ;
Brogan, MS ;
Brisley, RJ ;
Webster, DE .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1995, 7 (1-2) :153-171
[5]  
ERTL G, 1997, HDB HETEROGENOUS CAT, V4
[6]   NOx storage in barium-containing catalysts [J].
Fridell, E ;
Skoglundh, M ;
Westerberg, B ;
Johansson, S ;
Smedler, G .
JOURNAL OF CATALYSIS, 1999, 183 (02) :196-209
[7]  
FRIDELL E, 1998, STUD SURF SCI CAT, V116
[8]  
FRIDELL E, IN PRESS CATAL LETT
[9]   The current state of research on automotive lean NOx catalysis [J].
Fritz, A ;
Pitchon, V .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1997, 13 (01) :1-25
[10]  
HECK RM, 1995, CATALYTIC AIR POLLUT