Defluorination of graphite fluoride applying magnesium

被引：12

作者：

Koch, EC ^{[1
]}

机构：

[1] COMET GMBH Pyrotech Apparatebau, D-67307 Gollheim, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2001年 / 56卷 / 06期

关键词：

graphite fluoride; defluorination; magnesium;

D O I：

10.1515/znb-2001-0606

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Consolidated stoichiometric mixtures of graphite fluoride (1) and magnesium (2) upon ignition under argon atmosphere (0,1 MPa) yield very high flame temperature of similar to 5600 K as determined by infrared emission spectroscopy. The combustion product was analysed by X-ray powder diffraction and revealed the presence of magnesium fluoride and graphite as well as structurally low ordered carbon. A possible reaction mechanism is discussed.

引用

页码：512 / 516

页数：5

共 21 条

[1]

BERNIER P, 1997, CARBONE TOUT ETATS, P172

[2]

DADIEU A, 1968, RAKETENTREIBSTOFFE, P189

[3] POLY(CARBON MONOFLUORIDE) - SOLID, LAYERED FLUOROCARBON [J].

KAMARCHIK, P ;

MARGRAVE, JL .

ACCOUNTS OF CHEMICAL RESEARCH, 1978, 11 (08) :296-300

[4] ELECTRON-AFFINITIES AND ELECTRON-TRANSFER REACTIONS [J].

KEBARLE, P ;

CHOWDHURY, S .

CHEMICAL REVIEWS, 1987, 87 (03) :513-534

[5]

Koch E.-C., 2000, 10 GDCH VORTR AN FUN, pA62

[6]

Koch E.-C., 1999, DE Patent, Patent No. [19,964,172, 19964172]

[7]

Koch EC, 2000, PROPELL EXPLOS PYROT, V25, P37, DOI 10.1002/(SICI)1521-4087(200001)25:1<37::AID-PREP37>3.3.CO

[8]

2-R

[9]

Koch EC, 2001, PROPELL EXPLOS PYROT, V26, P3, DOI 10.1002/1521-4087(200101)26:1<3::AID-PREP3>3.0.CO

[10]

2-8

← 1 2 3 →