Lifting the lid on metatungstate.: 1H and 183W NMR study of the six electron reduced anion [(H)2{WIV3(OH2)3}WVI9O34(OH)3]3-

被引：5

作者：

Boskovic, C

Sadek, M ^{[1
]}

Brownlee, RTC

Bond, AM

Wedd, AG

机构：

[1] Univ Melbourne, Sch Chem, Parkville, Vic 3052, Australia

[2] La Trobe Univ, Dept Chem, Bundoora, Vic 3083, Australia

[3] Monash Univ, Dept Chem, Clayton, Vic 3168, Australia

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 06期

关键词：

D O I：

10.1039/a900088g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The distribution of the eleven protons present in a six-electron reduced form of metatungstate, [(H)(2){W-3(IV)-(OH2)(3)}(W9O34)-O-VI(OH)(3)](3-), in dry CD3CN is mapped by H-1 and W-183 NMR, allowing assessment of structural changes which accompany reduction.

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收藏

页码：533 / 534

页数：2

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