Photochemical and thermal isomerization of anionic azobenzene amphiphiles in homogeneous and aggregated systems

被引:5
作者
Kozlecki, T
Wilk, KA
Gancarz, R
机构
[1] Wroclaw Univ Technol, Inst Organ & Polymer Technol, PL-50370 Wroclaw, Poland
[2] Wroclaw Univ Technol, Inst Organ Chem Biochem & Biotechnol, PL-50370 Wroclaw, Poland
关键词
photochemical isomerization; thermal isomerization; anionic azobenzene; UV irradiation;
D O I
10.1016/S1010-6030(98)00302-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Kinetic and thermodynamic parameters of the trans-cis photoisomerization of trans-4-(4'-alkylphenylazo)phenyl derivatives (C(n)AzoX; n = 4, 8; X = SO3, COONa) by 366 nm UV irradiation as well as the cis-trans thermal reversion of the azobenzene moiety have been determined by means of the H-1 NMR technique in homogeneous and micellar systems of C(n)AzoX. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
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页码:229 / 234
页数:6
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