The effects of processing conditions on polymer photovoltaic device performance

被引:1
作者
Breeze, AJ [1 ]
Rumbles, G [1 ]
Gregg, BA [1 ]
Ginley, DS [1 ]
机构
[1] NREL, Golden, CO 80401 USA
来源
ORGANIC PHOTOVOLTAICS IV | 2004年 / 5215卷
关键词
polymer; small molecule organics; heterojunction; organic solar cells; polymer ordering;
D O I
10.1117/12.531846
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The work reported here explores the impact of polymer morphology on the physics and performance of perylene benzimidazole / poly(3-hexylthiophene) bilayer photovoltaic devices. By varying both the annealing temperature and the solvent used for polymer deposition, we demonstrate control of the polymer chain morphology. An increase in the relative ordering of the polymer chain conformation is observed through a shift in the absorption onset and absorption spectral shape, and results in improved photovoltaic performance.
引用
收藏
页码:271 / 275
页数:5
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