Polyfluoroorganoboron oxygen compounds, part 3. The palladium-catalysed cross-coupling reaction of lithium polyfluorophenyltrimethoxyborates with 4-fluoroiodobenzene

被引：24

作者：

Frohn, HJ

Adonin, NY

Bardin, VV

Starichenko, VF

机构：

[1] Univ Duisburg Gesamthsch, Inst Chem, D-47048 Duisburg, Germany

[2] RAS, SB, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2003年 / 122卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

polyfluoroarylborates; methoxyborates; cross-coupling; polyfluorobiphenyls; palladium catalysis; silver oxide;

D O I：

10.1016/S0022-1139(03)00088-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Li[C6F5B(OMe)(3)]. Li[C6HF4B(OMe)(3)] (all three isomers) and Li[3,4,5-C6H2F3B(OMe)(3)] are the first examples of polyfluorophenyltrimethoxyborate salts which have been applied as reagents to Pd-catalysed cross-coupling reactions. A series of polyfluorinated biphenyls C6H5-nFn-C6H4F-4' were obtained from Li[C6H5-nFnB(OMe)(3)] and the model substrate 4-FC6H4I in the presence of Pd catalysts. The influence of the number and the position of fluorine atoms in the polyfluorophenyltrimetboxyborate salts on the reactivity in the coupling reaction was elucidated. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：195 / 199

页数：5

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