13C NMR chemical shift of single-wall carbon nanotubes

被引:55
作者
Latil, S [1 ]
Henrard, L
Bac, CG
Bernier, P
Rubio, A
机构
[1] Univ Montpellier 2, Dynam Phases Condensees Grp, CNRS, F-34095 Montpellier 5, France
[2] Fac Univ Notre Dame Paix, Lab Phys Solide, B-5000 Namur, Belgium
[3] Donostia Int Phys Ctr, San Sebastian 20018, Basque Country, Spain
[4] UPV, EHU, CSIC, Ctr Mixto, San Sebastian 20018, Basque Country, Spain
关键词
D O I
10.1103/PhysRevLett.86.3160
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We compute the magnetic shielding tenser within the London approximation and estimate the Knight shift of single-wall carbon nanotubes. Our results indicate that high resolution C-13 NMR should be able to separate the metallic and insulator character of the nanotubes since a 11 ppm splitting is predicted from the respective resonances. As a model for disorder, bending, and defects in these structures, we investigate the magnetic response of nanotubes with finite size. We get a small line broadening coming from an intrinsic length dependent resonance effect. The nanotube packing is also studied and leads to a 20 ppm broadening which disappears under experimental high-resolution conditions.
引用
收藏
页码:3160 / 3163
页数:4
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