Raman and x-ray diffraction studies of nanometric Sn2P2S6 crystals

被引:16
作者
Gomonnai, AV
Azhniuk, YM
Vysochanskii, YM
Kikineshi, AA
Kis-Varga, M
Daroczy, L
Prits, IP
Voynarovych, IM
机构
[1] Natl Acad Sci Ukraine, Inst Electron Phys, UA-88017 Uzhgorod, Ukraine
[2] Uzhgorod Natl Univ, UA-88000 Uzhgorod, Ukraine
[3] Hungarian Acad Sci, Inst Nucl Res, H-4001 Debrecen, Hungary
[4] Univ Debrecen, Dept Solid State Phys, H-4010 Debrecen, Hungary
关键词
D O I
10.1088/0953-8984/15/37/006
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Nanometric Sn2P2S6 crystalline powders and ceramics are studied by x-ray diffraction and Raman spectroscopy. The average crystallite size is estimated from TEM and x-ray data. The observed features in the Raman spectra are discussed in view of confinement-related selection rules relaxation, surface phonon modes and possible partial substitution of sulfur by oxygen at the nanometric powder surface.
引用
收藏
页码:6381 / 6393
页数:13
相关论文
共 48 条
  • [1] BAKKER H, 1992, SOLID STATE PHENOM, V23, P253
  • [2] Temperature investigations of the ferroelectric crystals Sn2P2S6 and Sn2P2Se6 by means of 119Sn Mossbauer spectroscopy
    Baltrunas, D
    Grabar, AA
    Mazeika, K
    Vysochanskii, YM
    [J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 1999, 11 (14) : 2983 - 2992
  • [3] Multilevel genetic-algorithm optimization of the thermodynamic analysis of the incommensurate phase in ferroelectric Sn2P2Se6 -: art. no. 064103
    Berezovsky, SV
    Korda, VY
    Klepikov, VF
    [J]. PHYSICAL REVIEW B, 2001, 64 (06)
  • [4] LATTICE-DYNAMICS OF LAYERED MPX3 (M=MN,FE,NI,ZN, X=S,SE) COMPOUNDS
    BERNASCONI, M
    MARRA, GL
    BENEDEK, G
    MIGLIO, L
    BALKANSKI, M
    SCAGLIOTTI, M
    JULIEN, C
    JOUANNE, M
    [J]. PHYSICAL REVIEW B, 1988, 38 (17): : 12089 - 12099
  • [5] Soft-chemistry forms of Sn2P2S6 and CuInP2S6
    Bourdon, X
    Cajipe, VB
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1998, 141 (01) : 290 - 293
  • [6] Room-temperature synthesis of Sn2P2S6
    Bourdon, X
    Prouzet, E
    Cajipe, VB
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1997, 129 (01) : 157 - 159
  • [7] THE EFFECTS OF MICROCRYSTAL SIZE AND SHAPE ON THE ONE PHONON RAMAN-SPECTRA OF CRYSTALLINE SEMICONDUCTORS
    CAMPBELL, IH
    FAUCHET, PM
    [J]. SOLID STATE COMMUNICATIONS, 1986, 58 (10) : 739 - 741
  • [8] Photovoltaic effect of Sn2P2S6 ferroelectric crystal and ceramics
    Cho, YW
    Choi, SK
    Vysochanskii, YM
    [J]. JOURNAL OF MATERIALS RESEARCH, 2001, 16 (11) : 3317 - 3322
  • [9] Eijt SWH, 1998, EUR PHYS J B, V5, P169, DOI 10.1007/s100510050431
  • [10] Soft modes and phonon interactions in Sn2P2Se6 studied by means of neutron scattering
    Eijt, SWH
    Currat, R
    Lorenzo, JE
    Saint-Gregoire, P
    Katano, S
    Janssen, T
    Hennion, B
    Vysochanskii, YM
    [J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 1998, 10 (22) : 4811 - 4844