Experimental and theoretical study of the XYO (X, Y = Cl, Br) light-induced interconversion in argon matrix

被引：6

作者：

Chaquin, P

Alikhani, ME

Bahou, M

Schriver-Mazzuoli, L

Schriver, A

机构：

[1] Univ Paris 06, UP CNRS 9070, Chim Theor Lab, F-75252 Paris 05, France

[2] Univ Paris 06, Lab Spectrochim Mol, F-75252 Paris, France

[3] Univ Paris 06, UP CNRS 136, Lab Phys Mol & Applicat, F-75252 Paris 05, France

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 1998年 / 102卷 / 43期

关键词：

D O I：

10.1021/jp980952f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The complex ClBrO has been generated in argon matrix by photolysis of the O-3:BrCl complex and has been characterized by its Fourier-transform IR spectrum. Wavelength dependence of ClBrO photochemistry has been determined in the range from 317 to 870 nm by using laser irradiations and in the frequency region of a Nernst globar. Visible irradiation between 633 and 700 nm transforms ClBrO into BrClO and that above 700 nm continues the transformation into BrOCl. Reverse photoisomerization of BrOCl into ClBrO or BrClO was not observed. BrClO but not ClBrO is sensitive to IR irradiation. Calculations are combined with experimental observations to present a model for the photochemical isomerization of ClBrO and a comparison with related Cl2O and Br2O isomerizations.

引用

页码：8222 / 8229

页数：8

共 24 条

[1] PHOTOCHEMISTRY OF AN OZONE-BROMINE COMPLEX - THE IR-SPECTRUM OF MATRIX-ISOLATED BR2O [J].