Influence of Anionic and Nonionic Micelles upon Hydrolysis of 3-Hydroxy-Carbofuran

被引：16

作者：

Astray, G. ^{[1
]}

Cid, A. ^{[1
,2
]}

Manso, J. A. ^{[1
]}

Mejuto, J. C. ^{[1
,2
]}

Moldes, O. ^{[1
]}

Morales, J. ^{[1
]}

机构：

[1] Univ Vigo, Fac Ciencias, Dept Quim Fis, San Cibrao Das Vinas, Ourense, Spain

[2] Univ Vigo, Ctr Invest Transferencia & Innovac, San Cibrao Das Vinas, Ourense, Spain

来源：

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 2011年 / 43卷 / 08期

关键词：

NITROSO-P-TOLUENESULFONAMIDE; PERCOLATIVE PHENOMENA; PSEUDOPHASE APPROACH; BASIC DEGRADATION; REACTION MEDIA; MICROEMULSIONS; REACTIVITY; AOT; SYSTEMS; ACID;

D O I：

10.1002/kin.20563

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of nonionic and anionic micelles upon the stability of 3-hydroxy-carbofuran in basic media has been studied. The presence of micelles in the reaction medium implies a large inhibition of the basic hydrolysis of 3-hydroxy-carbofuran, due to the association of 3-hydroxy-carbofuran with the micellar core. The kinetic constants for the basic hydrolysis in these microheterogeneous media have been obtained on the basis of a micellar pseudophase model. (C) 2011 Wiley Periodicals, Inc. Int J Chem Kinet 43: 402-408, 2011

引用

页码：402 / 408

页数：7

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