Microscopic simulation of chemical bistability in homogeneous systems

被引：36

作者：

Baras, F ^{[1
]}

Mansour, MM ^{[1
]}

Pearson, JE ^{[1
]}

机构：

[1] LOS ALAMOS NATL LAB,LOS ALAMOS,NM 87545

来源：

JOURNAL OF CHEMICAL PHYSICS | 1996年 / 105卷 / 18期

关键词：

D O I：

10.1063/1.472679

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Microscopic simulation is used to clarify the status of stochastic theories of homogeneous chemical systems operating in the multiple steady state region. The results demonstrate the failure of the Langevin approach, but show excellent agreement with the master equation formulation. (C) 1996 American Institute of Physics.

引用

页码：8257 / 8261

页数：5

共 53 条

[1]

[Anonymous], 1973, J. Stat. Phys.

[2] VALIDITY OF MACROSCOPIC RATE-EQUATIONS IN EXOTHERMIC CHEMICAL-SYSTEMS [J].