Poly[(2-ethylhexyl acrylate)-ran-(tert-butyl acrylate)]-block-poly(2-cinnamoyloxyethyl acrylate) synthesis and properties

被引：10

作者：

Zheng, Ronghua ^{[1
]}

Liu, Guojun ^{[1
]}

Jao, Tze-Chi ^{[2
]}

机构：

[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada

[2] Afton Chem Corp, Fundamental Res Grp, Richmond, VA 23219 USA

来源：

POLYMER | 2007年 / 48卷 / 24期

基金：

加拿大自然科学与工程研究理事会;

关键词：

atom transfer radical polymerization; block copolymers; micellization;

D O I：

10.1016/j.polymer.2007.10.010

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly [(2-ethylhexyl acrylate)-ran-(tert-butyl acrylate)]-block-poly(2-cinnamoyloxyethyl acrylate) or P(EXA-r-tBA)-PCEA was synthesized by atom transfer radical polymerization. Reactivity ratios of EXA and tBA for copolymerization were determined. The specific refractive index increments of six diblocks were measured as a function of their composition. The diblocks were thermally stable and formed micelles in an automobile engine oil. Such micelles may be useful as an anti-friction additive in lubricating oils. (C) 2007 Elsevier Ltd. All rights reserved.

引用

页码：7049 / 7057

页数：9

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