Supramolecular AA-BB-Type Linear Polymers with Relatively High Molecular Weights via the Self-Assembly of Bis(m-phenylene)-32-Crown-10 Cryptands and a Bisparaquat Derivative

被引：256

作者：

Niu, Zhenbin ^{[1
]}

Huang, Feihe ^{[2
]}

Gibson, Harry W. ^{[1
]}

机构：

[1] Virginia Polytech Inst & State Univ, Dept Chem, Blacksburg, VA 24061 USA

[2] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 09期

基金：

美国国家科学基金会;

关键词：

HIGH-YIELD PREPARATION; CROWN-ETHER; ROTAXANES; PARAQUAT; HOST; 1ST; CRYPTAND/PARAQUAT; POLYMERIZATION; COMPLEXATION; DENDRIMERS;

D O I：

10.1021/ja110384v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two novel bis(m-phenylene)-32-crown-10-based cryptands, one bearing covalent linkages and the other metal-complex linkages, were designed and prepared. By self-assembly of these biscryptands, which can be viewed as AA monomers, and a bisparaquat, which can be viewed as a BB monomer, AA-BB-type linear supramolecular polymers with relatively high molecular weights were successfully prepared.

引用

页码：2836 / 2839

页数：4

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