Organic chemistry of subvalent transition metal complexes part 16 -: Novel synthesis of ansa-metallocenes via the reductive dimerization of fulvenes with group 4 metal divalent halides

被引：85

作者：

Eisch, JJ ^{[1
]}

Shi, X ^{[1
]}

Owuor, FA ^{[1
]}

机构：

[1] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 24期

关键词：

D O I：

10.1021/om980702l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Substituted ethylene-bridged ansa-metallocenes of group 4 dihalides can be prepared in high yields by the interaction of the titanium zirconium, or hafnium dihalide with 2 equiv of the appropriate fulvene. The requisite metal dihalides are readily produced by the alkylative reduction of the metal tetrahalide with 2 equiv of an alkyllithium reagent in THF or in toluene.

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页码：5219 / 5221

页数：3

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