Structure-property relationships on uniaxially oriented carbon nanotube/polyethylene composites

被引:61
作者
Gorrasi, Giuliana [1 ]
Di Lieto, Roberta [1 ]
Patimo, Giovanni [2 ]
De Pasquale, Salvatore [2 ]
Sorrentino, Andrea [1 ]
机构
[1] Univ Salerno, Dept Chem & Food Engn, I-84084 Salerno, Italy
[2] Univ Salerno, Dept Phys ER Caianiello, I-84084 Salerno, Italy
关键词
Carbon nanotube/polyethylene composites; High energy ball milling; Highly oriented polymeric films; NANOTUBE-EPOXY COMPOSITES; RAMAN-SPECTROSCOPY; MOLECULAR-ORIENTATION; POLYETHYLENE FILMS; NORMAL-ALKANES; HIGH-STRENGTH; N-PENTANE; POLYMERS; MORPHOLOGY; FIBERS;
D O I
10.1016/j.polymer.2011.01.008
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Multi walled carbon nanotubes have been incorporated into a linear low density polyethylene matrix through high energy ball milling technique at room temperature, without any chemical modification or physical treatment of the nanotubes. Highly oriented samples, with different draw ratios, were obtained by drawing at 80 degrees C the composite films. SEM and FTIR results on the drawn PE films demonstrate that the molecular chains in both crystalline and amorphous phases are well oriented along the drawing direction. The effect of different weight percent loadings of nanotubes and draw ratio on the morphology, thermal, mechanical and electrical properties of the composite fibers have been investigated. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1124 / 1132
页数:9
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