Laser pyrolysis of hydrocarbons in synthesis of soot containing fullerenes

被引：6

作者：

Cauchetier, M ^{[1
]}

Armand, X

Herlin, N

Alexandrescu, R

Morjan, I

Petcu, S

Voicu, I

机构：

[1] CEA, DSM, DRECAM, Serv Photons Atomes & Mol,CE Saclay, F-91191 Gif Sur Yvette, France

[2] Natl Inst Lasers Plasma & Radiat Devices, R-76900 Bucharest, Romania

来源：

FULLERENE SCIENCE AND TECHNOLOGY | 1999年 / 7卷 / 01期

关键词：

D O I：

10.1080/10641229909350272

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using a high power CW CO2 laser, the pyrolysis in a flow reactor of different hydrocarbons/oxidizer mixtures with/without sensitizer lead to soots containing weightable quantities of fullerenes which were identified by FTIR spectroscopy, high performance liquid chromatography (HPLC) and time-of-flight mass spectrometry. The C-60 and C-70 quantification was done by HPLC. The FTIR spectroscopy of toluene extracts from the soots and of exhaust gases allowed to discuss some aspects concerning the influence of sensitizer (SF6) addition as well as of the oxidiser (O-2/N2O) On the fullerene production in laser pyrolysis of benzene-based mixtures.

引用

页码：91 / 110

页数：20

共 21 条

[1]

ARMAND X, 1997, IN PRESS J PHYS CHEM

[2] NANOMETRIC BORON-NITRIDE POWDERS - LASER SYNTHESIS, CHARACTERIZATION AND FT-IR SURFACE STUDY [J].

BARATON, MI ;

BOULANGER, L ;

CAUCHETIER, M ;

LORENZELLI, V ;

LUCE, M ;

MERLE, T ;

QUINTARD, P ;

ZHOU, YH .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1994, 13 (04) :371-378

[3] LASER CHEMICAL VAPOR PRECIPITATION OF SUBMICROMETER SILICON AND SILICON-NITRIDE POWDERS FROM CHLORINATED SILANES [J].

BAUER, RA ;

SMULDERS, R ;

BECHT, JGM ;

VANDERPUT, PJ ;

SCHOONMAN, J .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1989, 72 (07) :1301-1304

[4] VIBRATIONAL RAMAN AND INFRARED-SPECTRA OF CHROMATOGRAPHICALLY SEPARATED C60 AND C70 FULLERENE CLUSTERS [J].

BETHUNE, DS ;

MEIJER, G ;

TANG, WC ;

ROSEN, HJ ;

GOLDEN, WG ;

SEKI, H ;

BROWN, CA ;

DEVRIES, MS .

CHEMICAL PHYSICS LETTERS, 1991, 179 (1-2) :181-186

[5] CONCENTRIC SHELLED AND PLATE-LIKE GRAPHITIC BORON-NITRIDE NANOPARTICLES PRODUCED BY CO2-LASER PYROLYSIS [J].

BOULANGER, L ;

ANDRIOT, B ;

CAUCHETIER, M ;

WILLAIME, F .

CHEMICAL PHYSICS LETTERS, 1995, 234 (1-3) :227-232

[6] NANOCOMPOSITE SI/C/N POWDER PRODUCTION BY LASER-AEROSOL INTERACTION [J].

CAUCHETIER, M ;

CROIX, O ;

HERLIN, N ;

LUCE, M .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1994, 77 (04) :993-998

[7]

EBRECHT M, 1993, CHEM PHYS LETT, V214, P34

[8] POLYHEDRAL CARBON-IONS IN HYDROCARBON FLAMES [J].

GERHARDT, P ;

LOFFLER, S ;

HOMANN, KH .

CHEMICAL PHYSICS LETTERS, 1987, 137 (04) :306-310

[9]

Haggerty J. S., 1981, LASER INDUCED CHEM P

[10] FULLERENES C60 AND C70 IN FLAMES [J].

HOWARD, JB ;

MCKINNON, JT ;

MAKAROVSKY, Y ;

LAFLEUR, AL ;

JOHNSON, ME .

NATURE, 1991, 352 (6331) :139-141

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