Amide from dinitrogen by in situ cleavage and partial hydrogenation promoted by a transient zero-valent thorium synthon

被引：78

作者：

Korobkov, I ^{[1
]}

Gambarotta, S ^{[1
]}

Yap, GPA ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 40期

关键词：

nitrogen; O ligands; subvalent compounds; synthons; thorium;

D O I：

10.1002/anie.200352205

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduction through cleavage: The reduction of a tetravalent thorium-bisdiaryloxide complex 1 with [K(naphthalenide)] leads to the cleavage of dinitrogen and partial hydrogenation via the probable formation of a zero-valent thorium-amide synthon (2; see scheme).

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页码：4958 / 4961

页数：4

相关论文

共 37 条

[1]

[Anonymous], 2003, ANGEW CHEM, V115, P838

[2] NITROGEN-FIXATION IN SOLUTION [J].

BAZHENOVA, TA ;

SHILOV, AE .

COORDINATION CHEMISTRY REVIEWS, 1995, 144 :69-145

[3] THE SYNTHESIS AND CHARACTERIZATION, INCLUDING X-RAY-DIFFRACTION STUDY, OF [TH(ETA-C5H3(SIME3)2)3] - THE 1ST THORIUM(III) CRYSTAL-STRUCTURE [J].

BLAKE, PC ;

LAPPERT, MF ;

ATWOOD, JL ;

ATWOOD, JL ;

ZHANG, HM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (15) :1148-1149

[4] MOLECULAR-STRUCTURE OF AN UNUSUAL ORGANOACTINIDE HYDRIDE COMPLEX DETERMINED SOLELY BY NEUTRON-DIFFRACTION [J].

BROACH, RW ;

SCHULTZ, AJ ;

WILLIAMS, JM ;

BROWN, GM ;

MANRIQUEZ, JM ;

FAGAN, PJ ;

MARKS, TJ .

SCIENCE, 1979, 203 (4376) :172-174

[5] Dinitrogen rearranging over a metal-oxo surface and cleaving to nitride:: From the end-on to the side-on bonding mode, to the stepwise cleavage of the NN bonds assisted by NbIII-calix[4]arene [J].

Caselli, A ;

Solari, E ;

Scopelliti, R ;

Floriani, C ;

Re, N ;

Rizzoli, C ;

Chiesi-Villa, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (15) :3652-3670

[6] Reductive cleavage of dinitrogen by a vanadium diamidoamine complex:: The molecular structures of [V(Me3SiN{CH2CH2NSiMe3}2)(μ-N)]2 and K[V(Me3SiN{ CH2CH2NSiMe3}2)(μ-N)]2 [J].

Clentsmith, GKB ;

Bates, VME ;

Hitchcock, PB ;

Cloke, FGN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (44) :10444-10445

[7] Reversible binding and reduction of dinitrogen by a uranium(III) pentalene complex [J].

Cloke, FGN ;

Hitchcock, PB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (32) :9352-9353

[8] FORMALLY TETRAVALENT CERIUM AND THORIUM COMPOUNDS - A CONFIGURATION-INTERACTION STUDY OF CEROCENE CE(C8H8)(2) AND THOROCENE TH(C8H8)(2) USING ENERGY-ADJUSTED QUASI-RELATIVISTIC AB-INITIO PSEUDOPOTENTIALS [J].

DOLG, M ;

FULDE, P ;

STOLL, H ;

PREUSS, H ;

CHANG, A ;

PITZER, RM .

CHEMICAL PHYSICS, 1995, 195 (1-3) :71-82

[9]

Fryzuk M. D., 2002, ANGEW CHEM, V114, P3861

[10] Nitride formation by thermolysis of a kinetically stable niobium dinitrogen complex [J].

Fryzuk, MD ;

Kozak, CM ;

Bowdridge, MR ;

Patrick, BO ;

Rettig, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (28) :8389-8397

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