Polyisobutylene-block-poly(ethylene oxide) for robust templating of highly ordered mesoporous materials

被引：84

作者：

Groenewolt, M

Brezesinski, T

Schlaad, H

Antonietti, M

Groh, PW

Iván, B

机构：

[1] Max Planck Inst Colloids & Interfaces, D-14476 Potsdam, Germany

[2] Hungarian Acad Sci, Dept Polymer Chem & Mat Sci, Inst Mat & Environm Chem, Chem Res Ctr, H-1525 Budapest, Hungary

来源：

ADVANCED MATERIALS | 2005年 / 17卷 / 09期

关键词：

D O I：

10.1002/adma.200401549

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Robust self-assembly with very high order is demonstrated by polyisobutylene-block-poly(ethylene oxide) (PIB-PEO) copolymers tailor-made by combining living cationic and anionic polymerization. A cubic micellar phase with long-range order and a glassy phase consisting of deformed spheroids are identified. Application of PIB-PEO in the synthesis of porous titanium oxide yields perfect anatase crystalline films with high regularity (see Figure).

引用

页码：1158 / +

页数：6

共 25 条

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