Construction of bridged polycyclic systems via radical cyclizations.: Uncovering of a novel carbocyclization-ring expansion sequence

被引：19

作者：

Rodríguez, JR

Castedo, L

Mascareñas, JL

机构：

[1] Univ Santiago de Compostela, Dept Quim Organ, Santiago De Compostela 15782, Spain

[2] Univ Santiago de Compostela, CSIC, Unidad Asociada, Santiago De Compostela 15782, Spain

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 08期

关键词：

D O I：

10.1021/ol015643d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

While exploring the application of radical cyclizations to the construction of bridged polycyclic systems, we have discovered a novel tandem process consisting of an endo-cyclization of a vinyl radical onto a terminal alkene followed by a one-carbon ring expansion promoted by the resulting secondary radical.

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收藏

页码：1181 / 1183

页数：3

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