209Bi NQR study of bismuth(III) complexes

被引：4

作者：

Zemnukhova, LA

Kuznetsov, SI

Davidovich, RL

机构：

[1] Russian Acad Sci, Inst Chem, Far Eastern Branch, Vladivostok 690022, Russia

[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1998年 / 47卷 / 11期

关键词：

Bi-209 NQR spectra; bismuth(III); complexes; complexonates; potassium pentafluorobismuthate(III); nitrate-chloride and sulfate-chloride bismuth(III) compounds;

D O I：

10.1007/BF02494274

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Potassium pentafluorobismuthate(III), nitrate-chloride Bi-III complexes MBiCl3NO3 (M = K, (NH2)(2)CNH2), sulfate-chloride Bi-III complexes MBiCl2SO4 (M = K, Rb, NH4, (NH2)(2)CNH2), and Bi-III complexonates with the anions of ethylenediaminetetraacetic acid M[Bi(edta)](2). nH(2)O (M = Mg, Ca, Ni, Cd) and nitrilotriacetic acid Bi(nta). 2H(2)O, and Bi(nta). 3thio . H2O (thio is thiourea) were studied by Bi-209 NQR spectroscopy. A second-order phase transition was observed in K2BiF5 at 100 K. The compounds Bi(nta). 2H(2)O, (NH2)(2)CNH2BiCl3NO3, and MBiCl2SO4 (M = K, NH4) are piezoelectrics.

引用

页码：2169 / 2172

页数：4

共 20 条

[1] CRYSTAL AND MOLECULAR-STRUCTURE OF KSBF3NO3 [J].

BOURGAULT, M ;

DUCOURANT, B ;

MASCHERPACORRAL, D ;

FOURCADE, R .

JOURNAL OF FLUORINE CHEMISTRY, 1981, 17 (03) :215-224

[2]

DAVIDOVICH RL, 1988, KOORDINATS KHIM+, V14, P1011

[3] METAL-COMPLEXES WITH MIXED ACIDO LIGANDS .11. NITRATOCHLORIDE COMPOUNDS OF BISMUTH(III) [J].

DAVIDOVICH, RL ;

MEDKOV, MA ;

IRKHINA, EB ;

TEPLUKHINA, LV .

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1986, 35 (07) :1325-1327

[4] COMPLEXES OF METALS WITH MIXED ACIDOLIGANDS .10. SULFATOCHLORIDE COMPLEXES OF BISMUTH [J].

DAVIDOVICH, RL ;

MEDKOV, MA ;

BOGOMOLOVA, EB ;

ZEMUKHOVA, LA .

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1984, 33 (05) :895-899

[5] SYNTHESIS AND STRUCTURE OF THE DOUBLE SULFATE RBSBF2SO4,CS5BF2SO4 [J].

FOURCADE, R ;

BOURGAULT, M ;

BONNET, B ;

DUCOURANT, B .

JOURNAL OF SOLID STATE CHEMISTRY, 1982, 43 (01) :81-86

[6] DEPENDENCE OF THE PURE QUADRUPOLE RESONANCE FREQUENCY ON PRESSURE AND TEMPERATURE [J].

KUSHIDA, T ;

BENEDEK, GB ;

BLOEMBERGEN, N .

PHYSICAL REVIEW, 1956, 104 (05) :1364-1377

[7]

LOGINOV AA, 1989, UKR KHIM ZH+, V55, P795

[8]

LOGINOV AA, 1989, UKR KHIM ZH+, V55, P1134

[9] CRYSTAL AND MOLECULAR STRUCTURE OF BISMUTH TRICHLORIDE [J].

NYBURG, SC ;

OZIN, GA ;

SZYMANSK.JT .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1971, B 27 (DEC15) :2298-&

[10] QUADRUPOLE SPECTRUM OF BICL3 [J].

ROBINSON, HG .

PHYSICAL REVIEW, 1955, 100 (06) :1731-1734

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