High efficiency and small roll-off electrophosphorescence from a new iridium complex with well-matched energy levels

被引:109
作者
Gao, Zhi Qiang [2 ]
Mi, Bao Xiu [1 ]
Tam, Hoi Lam [2 ]
Cheah, Kok Wai [2 ]
Chen, Chin Hsin [3 ]
Wong, Man Shing [4 ]
Lee, Shuit Tong [5 ]
Lee, Chun Sing [5 ]
机构
[1] Nanjing Univ Posts & Telecommun, Inst Adv Mat, Nanjing, Peoples R China
[2] Hong Kong Baptist Univ, Ctr Adv Luminescene Mat, Kowloon, Hong Kong, Peoples R China
[3] Natl Chiao Tung Univ, Display Inst, Microelect & Informat Syst Res Ctr, Hsinchu 300, Taiwan
[4] Hong Kong Baptist Univ, Dept Chem, Kowloon, Hong Kong, Peoples R China
[5] City Univ Hong Kong, Dept Phys & Mat Sci, Ctr Super Diamond & Adv Films COSDAF, Kowloon, Hong Kong, Peoples R China
关键词
D O I
10.1002/adma.200702343
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Phenylpyridazine ligands coordinating to the iridium(III) atom yield a thermally stable (5 % weight loss at 439 degrees C) homoleptic iridium complex with a high phosphorescent quantum yield (0.32 at room temperature). This material has well-matched energy levels with the host, and highly efficient electrophosphorescence (52 cd A(-1); see figure) with a small roll-off (23 % at 70 mA cm(-2)) in device efficiency is achieved.
引用
收藏
页码:774 / +
页数:6
相关论文
共 33 条
[1]   Electroluminescence mechanisms in organic light emitting devices employing a europium chelate doped in a wide energy gap bipolar conducting host [J].
Adachi, C ;
Baldo, MA ;
Forrest, SR .
JOURNAL OF APPLIED PHYSICS, 2000, 87 (11) :8049-8055
[2]   High efficiency single dopant white electrophosphorescent light emitting diodes [J].
Adamovich, V ;
Brooks, J ;
Tamayo, A ;
Alexander, AM ;
Djurovich, PI ;
D'Andrade, BW ;
Adachi, C ;
Forrest, SR ;
Thompson, ME .
NEW JOURNAL OF CHEMISTRY, 2002, 26 (09) :1171-1178
[3]   ELECTROLUMINESCENCE FROM SUBSTITUTED POLY(THIOPHENES) - FROM BLUE TO NEAR-INFRARED [J].
ANDERSSON, MR ;
BERGGREN, M ;
INGANAS, O ;
GUSTAFSSON, G ;
GUSTAFSSONCARLBERG, JC ;
SELSE, D ;
HJERTBERG, T ;
WENNERSTROM, O .
MACROMOLECULES, 1995, 28 (22) :7525-7529
[4]   Transient analysis of organic electrophosphorescence. II. Transient analysis of triplet-triplet annihilation [J].
Baldo, MA ;
Adachi, C ;
Forrest, SR .
PHYSICAL REVIEW B, 2000, 62 (16) :10967-10977
[5]   Very high-efficiency green organic light-emitting devices based on electrophosphorescence [J].
Baldo, MA ;
Lamansky, S ;
Burrows, PE ;
Thompson, ME ;
Forrest, SR .
APPLIED PHYSICS LETTERS, 1999, 75 (01) :4-6
[6]   Highly efficient phosphorescent emission from organic electroluminescent devices [J].
Baldo, MA ;
O'Brien, DF ;
You, Y ;
Shoustikov, A ;
Sibley, S ;
Thompson, ME ;
Forrest, SR .
NATURE, 1998, 395 (6698) :151-154
[7]   Transient analysis of organic electrophosphorescence: I. Transient analysis of triplet energy transfer [J].
Baldo, MA ;
Forrest, SR .
PHYSICAL REVIEW B, 2000, 62 (16) :10958-10966
[8]   Phosphorescent dyes for organic light-emitting diodes [J].
Chou, Pi-Tai ;
Chi, Yun .
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (02) :380-395
[9]   Highly efficient organic electrophosphorescent light-emitting diodes with a reduced quantum efficiency roll off at large current densities [J].
Cocchi, M ;
Fattori, V ;
Virgili, D ;
Sabatini, C ;
Di Marco, P ;
Maestri, M ;
Kalinowski, J .
APPLIED PHYSICS LETTERS, 2004, 84 (07) :1052-1054
[10]   EVIDENCE FOR STRONG MIXING BETWEEN THE LC AND MLCT EXCITED-STATES IN BIS(2-PHENYLPYRIDINATO-C2,N') (2,2'-BIPYRIDINE)IRIDIUM(III) [J].
COLOMBO, MG ;
HAUSER, A ;
GUDEL, HU .
INORGANIC CHEMISTRY, 1993, 32 (14) :3088-3092