Unprecedented efficient hydrogenation of arenes in biphasic liquid-liquid catalysis by re-usable aqueous colloidal suspensions of rhodium

被引:89
作者
Schulz, J [1 ]
Roucoux, A [1 ]
Patin, H [1 ]
机构
[1] Ecole Natl Super Chim Rennes, CNRS ESA 6052, Lab Chim Organ & Subst Nat, F-35700 Rennes, France
关键词
D O I
10.1039/a900551j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A reduced aqueous colloidal suspension of rhodium shows efficient activity for the catalytic hydrogenation of various benzene derivatives under biphasic conditions at room temperature and under atmospheric hydrogen pressure; the aqueous phase containing the Rh(0) particles can be re-used for further runs with a complete conservation of activity.
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页码:535 / 536
页数:2
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