2,5,8,11-Tetraboronic Ester Perylenediimides: A Next Generation Building Block for Dye-Stuff Synthesis

被引：97

作者：

Battagliarin, Glauco ^{[1
]}

Li, Chen ^{[1
]}

Enkelmann, Volker ^{[1
]}

Muellen, Klaus ^{[1
]}

机构：

[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 12期

关键词：

RUTHENIUM-CATALYZED CONVERSION; TRANSFER HYDROGENATION; BOND; TRANSISTORS; BISIMIDES; ALCOHOLS; KETONES; IMIDE; OXIME;

D O I：

10.1021/ol2008457

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Via an unprecedentedly reported ruthenium catalyzed reaction, an efficient and straightforward method was developed for the synthesis of 2,5,8,11-tetraboronate perylenediimide derivatives. A possible reaction mechanism is proposed. The synthesis of 2,5,8,11-tetra-lodo and totra-amino perylenedilmides derivatives is also reported.

引用

页码：3012 / 3015

页数：4

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