Attrition phenomena during fluidized bed combustion of granulated and mechanically dewatered sewage sludges

被引:15
作者
Cammarota, A
Chirone, R
Salatino, P [1 ]
Scala, F
Urciuolo, M
机构
[1] Univ Naples Federico II, Dipartimento Ingn Chim, I-80125 Naples, Italy
[2] CNR, Ist Ric Combust, I-00185 Rome, Italy
关键词
sewage sludge; fluidized bed; attrition; shrinking core;
D O I
10.1016/j.proci.2004.08.163
中图分类号
O414.1 [热力学];
学科分类号
摘要
Fluidized bed combustion of two types of sewage sludge was investigated in a bench scale reactor. The sludges differed as regards their preparation: one sludge was mechanically dewatered, the other was dried and granulated. The single particle conversion pattern and rate, and the nature and extent of attrition phenomena occurring during burn-off were quantitatively assessed. Primary fragmentation and conversion patterns of the residual char were characterized by periodic retrieval of fuel particles from the bed using a basket. Attrition by abrasion was assessed by collection of elutriated fines at the exhaust during batch fluidized bed combustion of chars of the two sludges. The size distribution of primary ash particles (PAPSD), relevant to bed inventory, particle size distribution, and balance between fly- and bottom-ash during steady fluidized bed combustion, was characterized using a purposely designed experimental procedure. Primary fragmentation was negligible for the granulated sludge, moderate for the mechanically dewatered one. Both sludges are characterized by the formation of coherent ash skeletons, responsible for a shrinking unreacted core conversion pattern of the char particles. Carbon attrition was very limited, as the coherent ash skeleton acted as a mechanical shield with respect to the unreacted carbon-rich core. The PAPSD closely followed the size distribution of the parent fuel particles for the granulated sludge, while it was slightly shifted to smaller sizes for the mechanically dewatered one. A simple combustion model, based on the shrinking core conversion model, has been developed to analyse the combustion behaviour of sludge char particles. The model is based on the consideration of resistances to mass transfer both in the boundary layer around the particle and in the carbon-depleted ash shell. The model satisfactorily reproduces the main features of the fluidized bed combustion of both sludges under the experimental conditions tested. (c) 2004 The Combustion Institute. Published by Elsevier Inc. All rights reserved.
引用
收藏
页码:3017 / 3024
页数:8
相关论文
共 14 条
[1]
BOUHAFID A, 2003, P 3 MED COMB S, V1, P219
[2]
CAMMAROTA A, 2001, P 16 INT C FLUID BED
[3]
CANO G, 2002, THESIS U NAPOLI FEDE
[4]
CHAR ATTRITION DURING THE BATCH FLUIDIZED-BED COMBUSTION OF A COAL [J].
CHIRONE, R ;
DAMORE, M ;
MASSIMILLA, L ;
MAZZA, A .
AICHE JOURNAL, 1985, 31 (05) :812-820
[5]
COMMINUTION OF CARBONS IN FLUIDIZED-BED COMBUSTION [J].
CHIRONE, R ;
MASSIMILLA, L ;
SALATINO, P .
PROGRESS IN ENERGY AND COMBUSTION SCIENCE, 1991, 17 (04) :297-326
[6]
Chirone R., 1984, P COMBUST INST, V20, P1505
[7]
FLUIDIZED-BED COMBUSTION OF HIGH ASH ANTHRACITE - ANALYSIS OF COMBUSTION EFFICIENCY AND PARTICLE-SIZE DISTRIBUTION [J].
JUNG, Y ;
PARK, D .
KOREAN JOURNAL OF CHEMICAL ENGINEERING, 1988, 5 (02) :109-115
[8]
LEE SH, 2000, ATTRITION PHENOMENA, P55
[9]
Levenspiel O., 1979, CHEM REACTION ENG, V3rd
[10]
Salatino P, 1998, TWENTY-SEVENTH SYMPOSIUM (INTERNATIONAL) ON COMBUSTION, VOLS 1 AND 2, P3103