Trichlorobis[2,6-di(phenylamino)pyridinato-N,N']tantalum(V) toluene solvate (1/1)

被引：12

作者：

Polamo, M

机构：

[1] Inorganic Chemistry Laboratory, Department of Chemistry, University of Helsinki, FIN-00014 Helsinki

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196011328

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [TaCl3(C17H14N3)(2)].C7H8, is formed when 2,6-bis(phenylamino)pyridine and tantalum(V) chloride are refluxed in toluene. The organic ligand loses an amino proton and forms a sigma bond with the metal atom, while its pyridine N atom acts as a donor. A small chelate ring is thus formed. The two bidentate ligands the three Cl atoms afford a seven-coordinate central atom.

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页码：2977 / 2980

页数：4

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