Performance of different crystal structures of PbO2 on electrochemical degradation of phenol in aqueous solution

被引:67
作者
Abaci, S [1 ]
Tamer, U
Pekmez, K
Yildiz, A
机构
[1] Hacettepe Univ, Dept Chem, Fac Sci, TR-06532 Ankara, Turkey
[2] Gazi Univ, Fac Pharm, Dept Pharmaceut Chem, TR-06330 Ankara, Turkey
关键词
alpha-PbO2; beta-PbO2; crystallinity; phenol degradation; benzoquinone;
D O I
10.1016/j.apsusc.2004.06.021
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Phenol degradation was carried out in acidic aqueous solution on different crystal structures of PbO2 surfaces at room temperature. Phenol, benzoquinone and maleic acid concentrations were monitored during the electrolysis process. It was determined that P surfaces have higher performance than alpha surfaces on phenol degradation. Then, the effect of crystallinities of pure beta-PbO2 surfaces was investigated and found that higher crystallinity increased the efficiency of the phenol degradation process. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:112 / 119
页数:8
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