Absolute configuration of 2,6-di-O-alkylgalactose obtained from peralkylated red algal polysaccharides

被引:17
作者
Errea, MI [1 ]
Kolender, AA [1 ]
Matulewicz, MC [1 ]
机构
[1] Univ Buenos Aires, Fac Ciencias Exactas & Nat, Dept Quim Organ, CONICET,CIHIDECAR, RA-1428 Buenos Aires, DF, Argentina
关键词
D O I
10.1515/BOT.2001.018
中图分类号
Q94 [植物学];
学科分类号
071001 [植物学];
摘要
A method to determine the proportion of both enantiomers of 2,6-di-O-alkylgalactose in a permethylated/perethylated polysaccharide is described. It involves conversion of the monosaccharides, obtained by hydrolysis of the sample, to the corresponding diastereomeric acetylated 1-deoxy-1-(1-phenylethylamino)alditols, followed by gas chromatographic analysis. This procedure has been applied to a polysaccharide isolated from Pteracladiella capillacea.
引用
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页码:133 / 138
页数:6
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