Regioselective homologation of bis(boronate) intermediates derived from rhodium-catalyzed diboration of simple alkenes

被引：20

作者：

Kalendra, DM ^{[1
]}

Dueñes, RA ^{[1
]}

Morken, JP ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

来源：

SYNLETT | 2005年 / 11期

关键词：

boron; asymmetric catalysis; silicon; regioselectivity; alkenes;

D O I：

10.1055/s-2005-869873

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Regioselective homologation of alkyl-1,2-bis(catecholboronates) may be accomplished by treatment of these reactive intermediates with TMSCHN2. A convenient process is reported where alkene diboration and the subsequent homologation reaction are accomplished in the same reaction flask.

引用

页码：1749 / 1751

页数：3

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