Vapor-phase infrared spectral study of analogs of the nerve agent sarin

被引:12
作者
McGarvey, DJ
Stuff, JR
Williams, BR
Durst, HD
机构
[1] EAI Corp, Abingdon, MD 21009 USA
[2] Edgewood Chem & Biol Ctr, Aberdeen Proving Ground, MD 21010 USA
关键词
FTIR; infrared; chemical warfare agents; Sarin; spectra; gas chromatography;
D O I
10.1080/00387010009350158
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Analogs of the chemical warfare agent Sarin were synthesized using a microscale technique and analyzed with a gas chromatograph equipped with a light pipe Fourier Transform infrared spectrometer. Produced as byproducts of the chemical warfare agents, a variety of related organophosphonate byproducts were often also observed. Similarities and differences among the spectra within the classes are noted, including some distinguishing characteristics of the infrared spectra not previously cited in the literature.
引用
收藏
页码:795 / 819
页数:25
相关论文
共 20 条
[1]  
AARON HS, 1996, REC ORG PROH CHEM WE
[2]  
CHADWICK E, 1998, P 4 JOINT WORKSH STA
[3]  
Colthup N.B., 1990, INTRO INFRARED RAMAN
[4]  
Corbrjdge D.E.C., 1956, J APPL CHEM, V6, P456
[5]   INFRARED SPECTRA OF PHOSPHORUS COMPOUNDS [J].
DAASCH, LW ;
SMITH, DC .
ANALYTICAL CHEMISTRY, 1951, 23 (06) :853-868
[6]  
Durst HD, 1998, ANAL LETT, V31, P1429
[7]  
HERRES W, 1987, HRGC FTIR CAPILLARY
[8]  
HOLMAN M, 1972, CHEM ANAL SERIES ANA
[9]   STUDIES IN STEROID METABOLISM .30. THE INFRARED SPECTRA OF ACETOXYSTEROIDS BELOW 1350 CM [J].
JONES, RN ;
HERLING, F .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (06) :1152-1161
[10]  
LEIBRAND RJ, 1993, BASICS GC IRD GC IRD