A general approach to the size- and shape-controlled synthesis of platinum nanoparticles and their catalytic reduction of oxygen

被引：756

作者：

Wang, Chao ^{[1
]}

Daimon, Hideo ^{[2
]}

Onodera, Taigo ^{[2
]}

Koda, Tetsunori ^{[1
,2
]}

Sun, Shouheng ^{[1
]}

机构：

[1] Brown Univ, Dept Chem, Providence, RI 02912 USA

[2] Hitachi Maxell Ltd, Technol & Dev Div, Ibaraki 3002496, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 19期

关键词：

fuel cells; heterogeneous catalysis; nanoparticles; oxygen; platinum;

D O I：

10.1002/anie.200800073

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic cobblestones: Monodisperse platinum nanoparticles were prepared with controlled sizes (3-7 nm) and shapes (polyhedron, truncated cube, or cube). The cubic nanoparticles are a much more active cathode catalyst for the oxygen reduction reaction: the current density J from 7 nm cubes is four times that of the other shapes (see picture), indicating great potential for fuel cell applications. (Graph Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3588 / 3591

页数：4

共 30 条

[1] Shape-controlled synthesis of colloidal platinum nanoparticles
Ahmadi, TS
Wang, ZL
Green, TC
Henglein, A
ElSayed, MA
[J]. SCIENCE, 1996, 272 (5270) : 1924 - 1926
[2] Bard A. J., 2001, ELECTROCHEMICAL METH, P44
[3] Recent advances in materials for fuel cells
Brandon, NP
Skinner, S
Steele, BCH
[J]. ANNUAL REVIEW OF MATERIALS RESEARCH, 2003, 33 : 183 - 213
[4] Platinum nanoparticle shape effects on benzene hydrogenation selectivity
Bratlie, Kaitlin M.
Lee, Hyunjoo
Komvopoulos, Kyriakos
Yang, Peidong
Somorjai, Gabor A.
[J]. NANO LETTERS, 2007, 7 (10) : 3097 - 3101
[5] Chen J., 2005, ANGEW CHEM, V117, P2645
[6] Pt nanoparticles surfactant-directed assembled into colloidal spheres and used as substrates in forming Pt nanorods and nanowires
Chen, Jingyi
Xiong, Yujie
Yin, Yadong
Xia, Younan
[J]. SMALL, 2006, 2 (11) : 1340 - 1343
[7] Polyol synthesis of platinum nanostructures: Control of morphology through the manipulation of reduction kinetics
Chen, JY
Herricks, T
Xia, YN
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (17) : 2589 - 2592
[8] Electro-oxidation of formic acid catalyzed by FePt nanoparticles
Chen, Wei
Kim, Jaemin
Sun, Shouheng
Chen, Shaowei
[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (23) : 2779 - 2786
[9] ADSORPTION OF BISULFATE ANION ON A PT(100) ELECTRODE - A COMPARISON WITH PT(111) AND PT(POLY)
GAMBOAALDECO, ME
HERRERO, E
ZELENAY, PS
WIECKOWSKI, A
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 348 (1-2): : 451 - 457
[10] C-H bond functionalization in complex organic synthesis
Godula, K
Sames, D
[J]. SCIENCE, 2006, 312 (5770) : 67 - 72

← 1 2 3 →