Theory for the ultrafast ablation of graphite films

被引:155
作者
Jeschke, HO [1 ]
Garcia, ME [1 ]
Bennemann, KH [1 ]
机构
[1] Free Univ Berlin, Inst Theoret Phys, D-14195 Berlin, Germany
关键词
D O I
10.1103/PhysRevLett.87.015003
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The physical mechanisms for damage formation in graphite films induced by femtosecond laser pulses are analyzed using a microscopic electronic theory. We describe the nonequilibrium dynamics of electrons and lattice by performing molecular dynamics simulations on time-dependent potential energy surfaces. We show that graphite has the unique property of exhibiting two distinct laser-induced structural instabilities. For high absorbed energies (>3.3 eV/atom) we find nonequilibrium melting followed by fast evaporation. For low intensities above the damage threshold (>2.0 eV/atom) ablation occurs via removal of intact graphite sheets.
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页数:4
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共 23 条
[1]   EMPIRICAL POTENTIAL FOR HYDROCARBONS FOR USE IN SIMULATING THE CHEMICAL VAPOR-DEPOSITION OF DIAMOND FILMS [J].
BRENNER, DW .
PHYSICAL REVIEW B, 1990, 42 (15) :9458-9471
[2]   GRAPHITE INTERPLANAR BONDING - ELECTRONIC DELOCALIZATION AND VAN-DER-WAALS INTERACTION [J].
CHARLIER, JC ;
GONZE, X ;
MICHENAUD, JP .
EUROPHYSICS LETTERS, 1994, 28 (06) :403-408
[3]   A microscopic model for surface-induced diamond-to-graphite transitions [J].
DeVita, A ;
Galli, G ;
Canning, A ;
Car, R .
NATURE, 1996, 379 (6565) :523-526
[4]   Liquid-liquid phase transformation in carbon [J].
Glosli, JN ;
Ree, FH .
PHYSICAL REVIEW LETTERS, 1999, 82 (23) :4659-4662
[5]  
HORWITZ JS, 1999, APPL PHYS A, V69
[6]   Microscopic analysis of the laser-induced femtosecond graphitization of diamond [J].
Jeschke, HO ;
Garcia, ME ;
Bennemann, KH .
PHYSICAL REVIEW B, 1999, 60 (06) :R3701-R3704
[7]   FEMTOSECOND CARRIER THERMALIZATION IN DENSE FERMI SEAS [J].
KNOX, WH ;
CHEMLA, DS ;
LIVESCU, G ;
CUNNINGHAM, JE ;
HENRY, JE .
PHYSICAL REVIEW LETTERS, 1988, 61 (11) :1290-1293
[8]  
Krüger J, 1999, LASER PHYS, V9, P30
[9]   Femtosecond optical breakdown in dielectrics [J].
Lenzner, M ;
Kruger, J ;
Sartania, S ;
Cheng, Z ;
Spielmann, C ;
Mourou, G ;
Kautek, W ;
Krausz, F .
PHYSICAL REVIEW LETTERS, 1998, 80 (18) :4076-4079
[10]   Time-resolved X-ray diffraction from coherent phonons during a laser-induced phase transition [J].
Lindenberg, AM ;
Kang, I ;
Johnson, SL ;
Missalla, T ;
Heimann, PA ;
Chang, Z ;
Larsson, J ;
Bucksbaum, PH ;
Kapteyn, HC ;
Padmore, HA ;
Lee, RW ;
Wark, JS ;
Falcone, RW .
PHYSICAL REVIEW LETTERS, 2000, 84 (01) :111-114