Formal synthesis of linderone and lucidone based on one-pot cyclizations of 1,3-bis-silyl enol ethers with oxalyl chloride

被引：15

作者：

Bose, G ^{[1
]}

Langer, P ^{[1
]}

机构：

[1] Univ Rostock, Inst Chem, D-18051 Rostock, Germany

来源：

SYNLETT | 2005年 / 06期

关键词：

acylcyclopentenediones; butenolides; cyclizations; natural products; silyl enol ethers;

D O I：

10.1055/s-2005-864803

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A formal synthesis of the acylcyclopentenediones linderone and lucidone is reported which is based on the cyclization of 2,4-bis(trimethylsilyloxy)-1,3,5-hexatrienes with oxalyl chloride and on the synthesis and functionalization of gamma-(2-silyloxyprope-nylidene)butenolides.

引用

收藏

页码：1021 / 1023

页数：3

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