Spectral assignments and reference data -: 1H and 13C NMR studies of asymmetrically substituted bis- and tris-Troger's bases

被引：7

作者：

Elguero, J

Fruchier, A

Mas, T

Pardo, C ^{[1
]}

机构：

[1] Univ Complutense, Fac Ciencias Quim, Dept Quim Organ 1, E-28040 Madrid, Spain

[2] Ctr Quim Organ Manuel Lora Tamayo, Inst Quim Med, E-28006 Madrid, Spain

[3] Ecole Natl Super Chim, F-34296 Montpellier, France

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 2005年 / 43卷 / 08期

关键词：

H-1; NMR; C-13; homoallylic couplings; bis-Troger's bases; tris-Troger's bases;

D O I：

10.1002/mrc.1619

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The H-1 and C-13 NMR spectra of two stereoisomeric bis-Troger's bases and four stereoisomeric tris-Troger's bases asymmetrically substituted on the external aromatic rings were recorded and the corresponding signals assigned. The relative configuration of the stereogenic units has been unequivocally determined on the basis of homoallylic couplings and NOE experiments. Copyright (c) 2005 John Wiley & Sons, Ltd.

引用

页码：665 / 669

页数：5

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