Growth of bipyramidal ruby crystals by the evaporation of A2O (A =Na, K)-MoO3 fluxes

被引:7
作者
Teshima, K [1 ]
Miyajima, A [1 ]
Kondo, H [1 ]
Mochizuki, K [1 ]
Suzuki, T [1 ]
Oishi, S [1 ]
机构
[1] Shinshu Univ, Fac Engn, Dept Environm Sci & Technol, Nagano 3808553, Japan
关键词
ruby crystal; flux evaporation; bipyramid; A(2)O-MoO3;
D O I
10.2109/jcersj.113.758
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Red and transparent ruby crystals have been successfully grown by a evaporation method of A(2)O (A = Na, K) - MoO3 fluxes. The grown crystals were up to 3.4 x 2.2 mm in size. The evaporation loss of the fluxes (A(2)O + MoO3) decreased linearly with an increase in the amount of A(2)O when the holding time was fixed at 5 h. As a result, relatively large crystals were grown from the A(2)O-MoO3 fluxes as compared with the solo MoO3 flux (max. 1.8 x 1.7 mm), because time to grow crystals could be lengthened. The influence of a variety of A(2)O On ruby crystal growth was hardly observed in our study. The basic form of the ruby crystals was a hexagonal bipyramid bounded by twelve well-developed [1123] faces, and showed the peculiar shape to the MoO3 system fluxes.
引用
收藏
页码:758 / 760
页数:3
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