Enantio- and diastereoselective reductive aldol reactions with iridium-pybox catalysts

被引：142

作者：

Zhao, CX ^{[1
]}

Duffey, MO ^{[1
]}

Taylor, SJ ^{[1
]}

Morken, JP ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Venable & Kenan Labs, Chapel Hill, NC 27599 USA

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 12期

关键词：

D O I：

10.1021/ol015859f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A catalytic amount of [(cod)IrCl](2) and indane-pybox converts diethylmethylsilane, methyl acrylate, and certain aldehydes to the derived reductive aldol adduct with good enantio and diastereocontrol.

引用

页码：1829 / 1831

页数：3

共 35 条

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