Gas phase reactions of CF3O- and CF3O-•H2O and their relevance to the detection of stratospheric HCl

被引：13

作者：

Amelynck, C ^{[1
]}

Van Bavel, AM ^{[1
]}

Schoon, N ^{[1
]}

Arijs, E ^{[1
]}

机构：

[1] Inst Aeron Spatiale Belgique, B-1180 Brussels, Belgium

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY | 2000年 / 202卷 / 1-3期

关键词：

ion/molecule reactions; chemical ionization; stratospheric trace constituents;

D O I：

10.1016/S1387-3806(00)00244-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The reactions of CF3O-, CF3O-.H2O and CF3O-. HF with HCl and of CF3O- with H2O have been studied at room temperature in a flowing afterglow instrument. All reactions with HCl proceed at the gas kinetic rate. The reaction of CF3O- with HCl proceeds by fluoride transfer, whereas CF3O-.H2O and CF3O-. HF react with HCl by ligand switching. The Gibbs free energy change of the reaction of CF3O- with H2O has been determined at room temperature as well as the collisional dissociation rate constant of CF3O-.H2O ions. (Int J Mass Spectrom 202 (2000) 207-216) (C) 2000 Elsevier Science B.V.

引用

页码：207 / 216

页数：10

共 22 条

[1] Seasonal variations of water vapor in the lower stratosphere inferred from ATMOS/ATLAS-3 measurements of H2O and CH4 [J].

Abbas, MM ;

Michelsen, HA ;

Gunson, MR ;

Abrams, MC ;

Newchurch, MJ ;

Salawitch, RJ ;

Chang, AY ;

Goldman, A ;

Irion, FW ;

Manney, GL ;

Moyer, EJ ;

Nagaraju, R ;

Rinsland, CP ;

Stiller, GP ;

Zander, R .

GEOPHYSICAL RESEARCH LETTERS, 1996, 23 (17) :2401-2404

[2] EXPERIMENTAL AND THEORETICAL INVESTIGATION OF DYNAMICS OF A FLOWING AFTERGLOW PLASMA [J].

ADAMS, NG ;

CHURCH, MJ ;

SMITH, D .

JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1975, 8 (12) :1409-1422

[3] Stratospheric chemical ionization mass spectrometry: nitric acid detection by different ion molecule reaction schemes [J].

Arijs, E ;

Barassin, A ;

Kopp, E ;

Amelynck, C ;

Catoire, V ;

Fink, HP ;

Guimbaud, C ;

Jenzer, U ;

Labonnette, D ;

Luithardt, W ;

Neefs, E ;

Nevejans, D ;

Schoon, N ;

Van Bavel, AM .

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 1998, 181 :99-111

[4] BALLOON-BORNE MASS-SPECTROMETER MEASUREMENTS OF HCL AND HF IN THE WINTER ARCTIC STRATOSPHERE [J].

ARNOLD, F ;

SPRENG, S .

GEOPHYSICAL RESEARCH LETTERS, 1994, 21 (13) :1255-1258

[5]

Chase Jr M.W., 1998, NIST JANAF THEMOCHEM, V9

[6]

Ferguson E., 1969, ADV ATOM MOL PHYS, V5, P1, DOI DOI 10.1016/S0065-2199(08)60154-2

[7] Reactions of CF3O- with atmospheric trace gases [J].

Huey, LG ;

Villalta, PW ;

Dunlea, EJ ;

Hanson, DR ;

Howard, CJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (01) :190-194

[8] Reactions of SiF5- with atmospheric trace gases: Ion chemistry for chemical ionization detection of HNO3 in the troposphere [J].

Huey, LG ;

Lovejoy, ER .

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1996, 155 (03) :133-140

[9] Fast time response measurements of HNO3 in air with a chemical ionization mass spectrometer [J].

Huey, LG ;

Dunlea, EJ ;

Lovejoy, ER ;

Hanson, DR ;

Norton, RB ;

Fehsenfeld, FC ;

Howard, CJ .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1998, 103 (D3) :3355-3360

[10]

HUEY LG, COMMUNICATION

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