Existence of the Schroeder paradox with a Nafion membrane? Small-angle x-ray scattering analysis

被引：13

作者：

Cornet, N ^{[1
]}

Gebel, G ^{[1
]}

de Geyer, A ^{[1
]}

机构：

[1] CEA Grenoble, Grp Polymere Conducteur Ion, Dept Rech Fondamentale, F-38054 Grenoble 9, France

来源：

JOURNAL DE PHYSIQUE IV | 1998年 / 8卷 / P5期

关键词：

D O I：

10.1051/jp4:1998509

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Water uptake of perfluorinated ionomer membranes (Nafion(R)) is studied by small angles X-rays scattering (SAXS). The purpose is to determine if these membranes are subjected to the Schroeder paradox. This paradox is defined as a difference of water uptake for a membrane immersed in water or balanced in presence of a satured vapor pressure. Results from SAXS measurements indicate that the appearance of the paradox is dependent on the pretraitement of the membrane because of its water uptake memory.

引用

页码：63 / 68

页数：6

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