Evidence for alternative mechanisms in the amino-Cope rearrangement

被引：9

作者：

Allin, SM ^{[1
]}

Button, MAC ^{[1
]}

机构：

[1] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 19期

关键词：

amino-Cope rearrangement; amino-diene; dissociation/recombination;

D O I：

10.1016/S0040-4039(99)00531-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The formal amino-Cope rearrangement of a 3-amino-1,5-diene substrate does not proceed solely by a concerted [3,3]-sigmatropic rearrangement mechanism. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：3801 / 3802

页数：2

共 6 条

[1]

Allin SM, 1998, SYNLETT, P1117

[2] The first example of asymmetric induction in an anionic amino-Cope rearrangement [J].

Allin, SM ;

Button, MAC .

TETRAHEDRON LETTERS, 1998, 39 (20) :3345-3348

[3]

Allin SM, 1997, SYNLETT, P725

[4] Stereoselective [2,3]-Wittig and tandem [2,3]-Wittig-anionic oxy-cope rearrangements of bis-allylic ethers: Effect of substituents [J].

Greeves, N ;

Lee, WM .

TETRAHEDRON LETTERS, 1997, 38 (36) :6445-6448

[5]

SPRULES TJ, 1993, TETRAHEDRON LETT, V34, P247

[6] New paradigm for anionic heteroatom cope rearrangements [J].

Yoo, HY ;

Houk, KN ;

Lee, JK ;

Scialdone, MA ;

Meyers, AI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (01) :205-206

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